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Ab initio Calculations Using Wien2k Code

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Spin-orbit interaction (or “coupling”)

This interaction is weaker than the Coulomb interaction and is responsible for the fine-structure of atomic lines.

How do we understand the spin-orbit interaction?

• The electron has a spin s, as well as orbital angular momentum l.
• For each angular momentum, there is an associated magnetic moment,  µl and µ s 
 • Spin-orbit = interaction between and Let’s start with the definition of magnetic moment….

To download the lecture click on the link below:


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